Abstract
Plasmonic nanoparticles (NPs), particularly Au NPs, are potential candidates for photocatalysts because of their unique optical properties. The size of Au NPs plays a crucial role in effective light absorption, which is an important factor in photocatalytic reactions. Although Au NP-based photocatalysts have garnered significant researched interest, the size effect of Au NPs on a photocatalytic reaction has not been sufficiently studied. We characterized the effect of size on the photocatalytic activity of Au NPs of different sizes. We found that the absorption cross-section of the Au NPs gradually increased as the size of the Au NPs increased. However, the reaction rate for each size of NP was inversely proportional to the absorption cross-section. Based on the simulation results, we found that larger Au NPs have a higher scattering factor than that of smaller Au NPs. Consequently, the scattering effect of Au NPs hinders effective light absorption, resulting in slower reaction kinetics. These findings can contribute to the rational design of high-efficiency plasmonic photocatalysts.
Subject
Physical and Theoretical Chemistry,Catalysis
Cited by
7 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献