Abstract
Copper(II) complex of the ligand possessing two enantiomerically pure trans-cyclohexane-1,2-diamine units proved to be an efficient catalyst for the enantioselective Henry reaction of aromatic aldehydes with nitromethane. The effect of various reaction conditions on yield and enantioselectivity of the Henry reaction was studied. The results suggest that only one cyclohexane-1,2-diamine unit is involved in catalysis of the Henry reaction.
Subject
Physical and Theoretical Chemistry,Catalysis
Reference35 articles.
1. Nitroaliphatic Compounds—Ideal Intermediates in Organic Synthesis?;Seebach;Chimia,1979
2. Comprehensive Organic Synthesis;Rosini,1991
3. The Henry reaction: recent examples
4. Formation synthétique d’alcools nitrés;Henry;C. R.,1895
5. Enantioselective synthesis of (R)-salmeterol employing an asymmetric Henry reaction as the key step
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