Ternary Composite of Polymer, Fullerene and Fluorinated Multi-Walled Carbon Nanotubes as the Active Layer of Organic Solar Cells

Author:

Kobeleva Elena S.1,Uvarov Mikhail N.1ORCID,Kravets Natalia V.12,Kulikova Aina V.12ORCID,Zinovyev Vladimir A.3ORCID,Gurova Olga A.4,Sysoev Vitalii I.4ORCID,Kondranova Anastasiya M.4,Kazantsev Maxim S.5ORCID,Degtyarenko Konstantin M.6,Matveeva Anna G.17ORCID,Kulik Leonid V.1ORCID

Affiliation:

1. V. V. Voevodsky Institute of Chemical Kinetics and Combustion of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

2. Novosibirsk State University, 630090 Novosibirsk, Russia

3. A. V. Rzhanov Institute of Semiconductor Physics of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

4. A. V. Nikolaev Institute of Inorganic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

5. N. N. Vorozhtsov Novosibirsk Institute of Organic Chemistry of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

6. Siberian Physico-Technical Institute, Tomsk State University, 634050 Tomsk, Russia

7. Institute of Solid State Chemistry and Mechanochemistry of the Siberian Branch of the Russian Academy of Sciences, 630090 Novosibirsk, Russia

Abstract

Fluorinated multi-walled carbon nanotubes are implemented as the third component of the active layer of organic solar cells. The addition of approximately 1% weight fraction of these nanotubes into PCDTBT/PC60BM polymer/fullerene active layer leads to a noticeable increase in the main photovoltaic parameters of the solar cells, including their stability. Presumably, the origins of this influence are optimizing the donor/acceptor composite morphology and reinforcing its structure with fluorinated multi-walled carbon nanotubes. This hypothesis is supported by the dramatic influence of the fluorinated multi-walled carbon nanotube additive on the kinetics of the decay of the EPR signal of light-induced charges in the PCDTBT/PC60BM composite.

Funder

RSF

Publisher

MDPI AG

Subject

Engineering (miscellaneous),Ceramics and Composites

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