Remediation of Heavy Metals Using Biomass-Based Adsorbents: Adsorption Kinetics and Isotherm Models

Author:

Abiodun Okon-Akan Omolabake123ORCID,Oluwaseun Oluwasogo4ORCID,Oladayo Olaoye Kayode12ORCID,Abayomi Omoogun5,George Akpowu Arubi6ORCID,Opatola Emmanuel7,Orah Robinson Friday8,Isukuru Efe Jeffery9ORCID,Ede Ifunanya Chiamaka10,Oluwayomi Oluwadara Temitayo8,Okolie Jude A.11,Omotayo Ibrahim Asiata3

Affiliation:

1. Forestry Research Institute of Nigeria, Ibadan, Nigeria

2. Department of Wood and Paper Technology, Federal College of Forestry, Jericho 200284, Nigeria

3. Pure and Applied Chemistry Department, Ladoke Akintola University of Technology, Ogbomosho 210214, Nigeria

4. Soil Science Laboratory, School of Applied Biosciences, Kyungpook National University, Sangju-si 37224, Republic of Korea

5. Department of Chemistry, University of Lagos, Lagos, Nigeria

6. Department of Chemistry, Federal University of Agriculture, Abeokuta 111101, Nigeria

7. Department of Materials and Metallurgical Engineering, University of Ilorin, Ilorin, Nigeria

8. Department of Chemistry, University of Ibadan, Ibadan 200132, Nigeria

9. Department of Environmental Management and Toxicology, Federal University of Petroleum Resources, Effurun 330102, Nigeria

10. Department of Chemistry, Federal University of Technology, Minna, Nigeria

11. Gallogly College of Engineering, University of Oklahoma, Norman, OK 73019, USA

Abstract

This study aims to comprehensively investigate the current advances in water treatment technologies for the elimination of heavy metals using biomass-based adsorbents. The enhancement of adsorption capacity in biomass materials is achieved through surface modification, which increases their porosity and surface area. The study therefore focuses on the impact of different surface modification techniques on the adsorption capacity, as well as the evaluation of adsorptive removal techniques and the analysis of various isotherm and kinetics models applied to heavy metal contaminants. The utilization of kinetic and isotherm models in heavy metal sorption is crucial as it provides a theoretical background to understand and predict the removal efficiency of different adsorbent materials. In contrast to previous studies, this research examines a wide range of adsorbent materials, providing a comprehensive understanding of their efficacy in removing heavy metals from wastewater. The study also delves into the theoretical foundations of the isotherm and kinetics models, highlighting their strengths, limitations, and effectiveness in describing the performance of the adsorbents. Moreover, the study sheds light on the regenerability of adsorbents and the potential for their engineering applications. Valuable insights into the state-of-the-art methods for heavy metal wastewater cleanup and the resources required for future developments were discussed.

Publisher

MDPI AG

Subject

Environmental Science (miscellaneous),Global and Planetary Change

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