An Experimental Study on the Kinetics of Leaching Ion-Adsorbed REE Deposits with Different Concentrations of Magnesium Sulfate

Abstract

As an important substitute for ammonium-free leaching, magnesium sulfate is applied as a leaching agent for the mining of ion-adsorbed REE (rare earth element) deposits. Upon deriving the equation regulating the leaching kinetics on the basis of the REE “shrinking core model” during the leaching process of magnesium sulfate, we conducted leaching experiments of natural particle-sized REE deposits by applying magnesium sulfate with concentrations of 1%, 2%, 3% and 4%. Hence, the leaching efficiencies and mass transfer rates were obtained. The results show that the hybrid control equation μδD1α+3μr2D21−23α−1−α23=3C0Mρr is applicable for describing the leaching process when the concentration of magnesium sulfate is 1%; when the concentrations reach 2%, 3% and 4%, the external diffusion control equation α=kt is appropriate to describe the leaching processes. The leaching efficiency of REE deposits reaches over 90%, specifically, 94.65%, 97.24% and 97.98%, when the concentration of magnesium sulfate is 2%, 3% and 4%, respectively. The maximum mass transfer rate appears when the concentration of magnesium sulfate is 4%, and the leaching time is reduced by 1.96 times compared to 1% concentration of magnesium sulfate. The results provide a favorable theoretical basis for the green and efficient extraction of ion-adsorbed REEs.