Abstract
Three complexes [Co(2-XPy)2Cl2] (X = Cl, Br, and I) were prepared and characterized, representing a rare case of isostructurality within the Cl-Br-I row. The nature of halogen bonding (XB) in a solid state was studied by DFT calculations, revealing a tendency of XB energy growth for heavier halogens.
Funder
Russian Foundation for Basic Research
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Cited by
30 articles.
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