Band Structure and Physical Properties of α-STF2I3: Dirac Electrons in Disordered Conduction Sheets

Author:

Naito ToshioORCID,Doi Ryusei

Abstract

The compound being investigated is an organic charge-transfer complex of the unsymmetrical donor STF with I3 [STF = bis(ethylenedithio)diselenadithiafulvalene], which is isostructural with α-ET2I3 and α-BETS2I3 [ET = bis(ethylenedithio)tetrathiafulvalene, BETS = bis(ethylenedithio)tetraselenafulvalene]. According to recent studies, the calculated band structure should represent a zero-gap semiconductor at 1 bar that is similar to α-ET2I3 under high pressure (>15 kbar). Such materials have attracted extensive interest because the electrons at the Fermi level can be massless Dirac fermions (MDFs), with relativistic behaviors like those seen in graphene. In fact, α-STF2I3 exhibited nearly temperature-independent resistivity, ρ, (~100–300 K), a phenomenon that is widely observed in zero-gap semiconductors. The non-Arrhenius-type increase in ρ (<~100 K) was consistent with the characteristics of interacting MDFs. The paramagnetic susceptibility, χ, (2–300 K)—as well as the reflectivity, R and optical conductivity, σ, (25–300 K; 400–25,000 cm−1)—were also almost temperature independent. Furthermore, σ was practically independent of wavenumber at ~6000–15,000 cm−1. There was no structural transition based on X-ray studies (90–300 K). Considering all the electrical, magnetic, optical and structural properties of α-STF2I3 at 1 bar, it was concluded that the salt possesses a band structure characterized with Dirac cones, which was consistent with the calculation.

Funder

Japan Society for the Promotion of Science

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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