Affiliation:
1. School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
2. China National Key Laboratory of Science and Technology on Materials under Shock and Impact, Beijing Institute of Technology, Beijing 100081, China
Abstract
Intermetallic compounds or solid solutions can form between Zr and Mo/W, in which the multiphase of the diffusion may be influenced by each other. Interdiffusion kinetic data in such intermetallic systems are highly demanded for material design. In this work, solid–solid diffusion couples of Zr-Mo and Zr-W were prepared by the fixture method, and the interdiffusion behaviors of Zr-Mo and Zr-W at 1300–1500 °C were systematically investigated. The results showed that the intermetallic compounds Mo2Zr/W2Zr formed in the Zr-Mo/W diffusion systems. The growth constants of the Mo2Zr and W2Zr phases varied with temperature in accordance with the Arrhenius relationship, and the activation energies of growth were 109 kJ/mol and 285 kJ/mol, respectively. In addition, (Zr, Mo) solid solution formed between Mo2Zr and pure Zr as diffusion proceeded, resulting in a lower chemical potential for the formation of Mo2Zr. The den Broeder method was used in calculating the interdiffusion coefficients of the solid solution. The results showed that the interdiffusion coefficient in the (Zr, Mo) solid solution decreased with the increase of Mo concentration. Moreover, the diffusion activation energy of the solid solution was evaluated based on the Arrhenius relationship, and the activation energy was 145–170 kJ/mol when the Mo content was in the range of 2–10 at. %. These diffusion kinetic data provide a reference for the composition design and preparation technic of Zr-based alloys.
Funder
National Natural Science Foundation of China
Science and Technological Innovation Program of Beijing Institute of Technology
Beijing Institute of Technology Research Fund Program for Young Scholars
Subject
Fluid Flow and Transfer Processes,Computer Science Applications,Process Chemistry and Technology,General Engineering,Instrumentation,General Materials Science
Cited by
1 articles.
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