A Column Leaching Model of Low-Grade Chalcopyrite Ore: Mineral Preferences and Chemical Reactivity

Abstract

Bioleaching models to examine copper extraction from low-grade chalcopyrite ores were set up to identify the influence of pyrite on leaching efficacy. A combination of scanning electron microscopy and geochemical analysis showed that extraction was marginally enhanced by the addition of pyrite when using a combination of Leptospirillum ferrooxidans, an iron oxidiser, Acidithiobacillus thiooxidans, a sulphur oxidising species and Acidithiobacillus ferrooxidans, an iron and sulphur oxidiser. Extensive biofilms formed on the pyrite surfaces (>106 cells/mm2) but were severely limited on chalcopyrite, possessing approximately the same number of cells as quartz grains, an internal non-nutrient control “substrate” (with ca. 2 × 103 cells/mm2). The presence of dissolved copper did not inhibit the growth of this consortium. Indirect “bioleaching” of chalcopyrite appears to be limited by proton activity at the chalcopyrite surface.