Self-Immobilizing Metals Binder for Construction Made of Activated Metallurgical Slag, Slag from Lignite Coal Combustion and Ash from Biomass Combustion

Abstract

Research on the effective use of secondary products is gaining more and more importance in Poland due to the intensively implementing idea of the circular economy. The solution used in this work are one of many tests useful in construction. The subject of this work was therefore the formation and testing of a new ecological construction binder, in particular for mortars or prefabricated elements working in the environment with high humidity. The binder was made of alkaline activated ground granular blast furnace slag (AAS), fly ash from biomass combustion (BFA) and furnace slag from brown coal combustion (LFS). The mixture was modified by introducing the zeolite to check the degree of metals immobilization contained in the ingredients of the mixture. A series of three mixtures were prepared: without and with zeolite soaked in distilled water or calcium nitrate. The strength of binders in time in dry and wet curing were tested and compared with the microstructure. The maximum compressive strength values at the eighth week were about 30 MPa. The strength values after 4 weeks of dry and wet curing were also compared. It was shown that 28-day wet curing increased the bending strength of the beams more than twice, but slightly decreased the compressive strength. The microstructure of the mixture with the highest values of compressive strength was the densest and the one with the lowest values of compressive strength, the most loosened with the most differentiated topographically fracture. The impregnation of zeolite with calcium nitrate decreased the compressive strength of the binder significantly. The bending strength of samples curing in dry conditions decreased during hardening. The results of the metals leaching test showed that the mixtures were safe for the environment, and due to the impregnation of zeolite with calcium nitrate, the binding effect of copper and zinc in the first weeks was greater than in the other mixtures.