Estimates of Hyperspectral Surface and Underwater UV Planar and Scalar Irradiances from OMI Measurements and Radiative Transfer Computations

Abstract

Quantitative assessment of the UV effects on aquatic ecosystems requires an estimate of the in-water hyperspectral radiation field. Solar UV radiation in ocean waters is estimated on a global scale by combining extraterrestrial solar irradiance from the Total and Spectral Solar Irradiance Sensor (TSIS-1), satellite estimates of cloud/surface reflectivity, ozone from the Ozone Monitoring Instrument (OMI) and in-water chlorophyll concentration from the Moderate Resolution Imaging Spectroradiometer (MODIS) with radiative transfer computations in the ocean-atmosphere system. A comparison of the estimates of collocated OMI-derived surface irradiance with Marine Optical Buoy (MOBY) measurements shows a good agreement within 5% for different seasons. To estimate scalar irradiance at the ocean surface and in water, we propose scaling the planar irradiance, calculated from satellite observation, on the basis of Hydrolight computations. Hydrolight calculations show that the diffuse attenuation coefficients of scalar and planar irradiance with depth are quite close to each other. That is why the differences between the planar penetration and scalar penetration depths are small and do not exceed a couple of meters. A dominant factor defining the UV penetration depths is chlorophyll concentration. There are other constituents in water that absorb in addition to chlorophyll; the absorption from these constituents can be related to that of chlorophyll in Case I waters using an inherent optical properties (IOP) model. Other input parameters are less significant. The DNA damage penetration depths vary from a few meters in areas of productive waters to about 30–35 m in the clearest waters. A machine learning approach (an artificial neural network, NN) was developed based on the full physical algorithm for computational efficiency. The NN shows a very good performance in predicting the penetration depths (within 2%).