Green and Efficient Utilization of Ferruginous Gibbsite Ore and Ferruginous Manganese Ore by Synergetic Carbothermic Co-Reduction–Magnetic Separation Process

Abstract

The synergetic utilization of ferruginous gibbsite ores (Al-Fe ores) and ferruginous manganese ores (Mn-Fe ores) by the carbothermic co-reduction roasting–magnetic separation process was proposed as an innovative and green process for the separation and recovery of the valuable metal elements of Mn, Fe and Al from these ores. In this paper, a ferromanganese crude alloy with 72.47% Fe and 10.19% Mn and a high recovery of 85.89% Fe was prepared, which produces an acceptable feed to produce manganese steels with an electric arc furnace. The synergistic co-reduction of the two kinds of complex and refractory minerals was favored to separate Fe, Mn and Al from these ores. The influence of the operating variables on the recovery and separation of valuable metals from Mn-Fe ores and Al-Fe ores is initially studied. Then, the stepwise reduction behaviors of a composite oxide Mn1-xFexO (0 ≤ x ≤ 1) and hercynite (Mn1−yFeyAl2O4, 0 ≤ y ≤ 1) were investigated to clarify that Mn-Fe ores have a positive impact on the reduction of fayalite and hercynite in Al-Fe ores. This study reported a simple green route, the carbothermic co-reduction–magnetic separation process, to economically and effectively treat Al-Fe ores and Mn-Fe ores.