Energy Integration of Thermal Pretreatment in Anaerobic Digestion of Wheat Straw

Author:

García Álvaro Alfonso12,Ruiz Palomar César12,Díaz Villalobos Israel23,Hermosilla Daphne4ORCID,Muñoz Raúl23,de Godos Ignacio12ORCID

Affiliation:

1. Department of Chemical Engineering and Environmental Technology, University of Valladolid (UVa), Campus Universitario Duques de Soria, 42004 Soria, Spain

2. Institute of Sustainable Process, University of Valladolid (UVa), 47011 Valladolid, Spain

3. Department of Chemical and Environmental Engineering, University of Valladolid (UVa), Dr. Mergelina s/n, 47011 Valladolid, Spain

4. Department of Forest and Environmental Engineering and Management, Universidad Politécnica de Madrid, José Antonio Novais 10, 28040 Madrid, Spain

Abstract

Cereal straw stands out as one of the most abundant and globally distributed agricultural residues. Traditional applications cope with a limited amount of production, leaving the remainder in the field for natural decomposition. Managing cereal straw through controlled biological transformation under anaerobic conditions holds the potential to generate added value in the form of bioenergy. However, the lignocellulosic composition of these substrates poses challenges for organic degradation, often requiring energy-intensive pretreatments. A detailed study with a comprehensive calculation of the overall energy balance of the integrated process is proposed, aiming to provide real added value and replicability. Three scenarios for wheat straw transformation were investigated, incorporating two preliminary pre-treatment stages—mechanical milling and physicochemical steam explosion. Three conditions of pretreatment were essayed, varying the time exposure of the steam explosion. The subsequent energy integration analysis revealed that the process was optimized by up to 15% in the final energy balance when the steam explosion was set to 10 min. The macromolecular composition determination revealed that the thermal pretreatment reduced the lag phase of the hydrolysis step through hemicellulose breakdown.

Publisher

MDPI AG

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