Spatial Distribution, Source Apportionment, Ozone Formation Potential, and Health Risks of Volatile Organic Compounds over a Typical Central Plain City in China

Abstract

The profiles, contributions to ozone formation, and associated health risks of 56 volatile organic compounds (VOCs) species were investigated using high time resolution observations from photochemical assessment monitoring stations (PAMs) in Luoyang, China. The daily averaged concentration of total VOCs (TVOCs) was 21.66 ± 10.34 ppbv in urban areas, 14.45 ± 7.40 ppbv in suburbs, and 37.58 ± 13.99 ppbv in an industrial zone. Overall, the VOCs levels in these nine sites followed a decreasing sequence of alkanes > aromatics > alkenes > alkyne. Diurnal variations in VOCs exhibited two peaks at 8:00–9:00 and 19:00–20:00, with one valley at 23:00–24:00. Source apportionment indicated that vehicle and industrial emissions were the dominant sources of VOCs in urban and suburban sites. The industrial site displayed extreme levels, with contributions from petrochemical-related sources of up to 38.3%. Alkenes and aromatics displayed the highest ozone formation potentials because of their high photochemical reactivity. Cancer and noncancer risks in the industrial site were higher than those in the urban and suburban areas, and USEPA possible risk thresholds were reached in the industrial site, indicating PAMs VOC–related health problems cannot be ignored. Therefore, vehicle and industrial emissions should be prioritized when considering VOCs and O3 control strategies in Luoyang.