Structural and Thermal Examinations of Polyamide Modified with Fly Ash from Biomass Combustion

Abstract

This paper presents the results of examinations of the structure and crystallinity of polyamide (PA6) modified with fly ash from biomass combustion in a fluidized-bed boiler. Composites based on a PA6 matrix were examined. They contained 5, 10, and 15 wt% fly ash. Fourier-transform infrared with attenuated total reflectance spectroscopy (FTIR-ATR) was used to identify the characteristic functional groups present in the chemical structure of polyamide and composites based on its matrix. Structural analysis was performed using a differential scanning calorimeter (DSC) and microscopic examinations. Analysis of the values of thermal effects determined using the DSC technique allowed for the evaluation of the degree of crystallinity of the materials studied. Polyamide is usually considered to be a two-phase system consisting of crystalline and amorphous regions. The addition of the filler in the form of fly ash reduced the degree of crystallinity of the studied specimens. Based on the FTIR-ATR spectra and the recorded DSC curves, it was found that the α-phase was the dominant crystalline phase in the studied materials. Microscopic examinations were conducted to analyze the microstructure of the materials, providing information on the distribution and shape of the filler particles. Most of the particles ranged in size from a few to tens of micrometers. Furthermore, the use of scanning electron microscopy coupled with energy-dispersive X-ray spectroscopy (SEM–EDS) allowed for the analysis of the distribution of chemical elements in selected filler particles.