The Superiority of TiO2 Supported on Nickel Foam over Ni-Doped TiO2 in the Photothermal Decomposition of Acetaldehyde

Abstract

Acetaldehyde decomposition was performed under heating at a temperature range of 25–125 °C and UV irradiation on TiO2 doped by metallic Ni powder and TiO2 supported on nickel foam. The process was carried out in a high-temperature reaction chamber, “The Praying MantisTM”, with simultaneous in situ FTIR measurements and UV irradiation. Ni powder was added to TiO2 in the quantity of 0.5 to 5.0 wt%. The photothermal measurements of acetaldehyde decomposition indicated that the highest yield of acetaldehyde conversion on TiO2 and UV irradiation was obtained at 75 °C. The doping of nickel to TiO2 did not increase its photocatalytic activity. Contrary to that, the application of nickel foam as a support for TiO2 appeared to be highly advantageous because it increased the decomposition of acetaldehyde from 31 to 52% at 25 °C, and then to 85% at 100 °C in comparison with TiO2 itself. At the same time, the mineralization of acetaldehyde to CO2 doubled in the presence of nickel foam. However, oxidized nickel foam used as support for TiO2 was detrimental. Most likely, different mechanisms of electron transfer between Ni–TiO2 and NiO-TiO2 occurred. The application of nickel foam greatly enhanced the separation of free carriers in TiO2. As a consequence, high yields from the photocatalytic reactions were obtained.