Comparison of Water-Removal Efficiency of Molecular Sieves Vibrating by Rotary Shaking and Electromagnetic Stirring from Feedstock Oil for Biofuel Production

Abstract

Adequate water-removal techniques are requisite to remain superior biofuel quality. The effects of vibrating types and operating time on the water-removal efficiency of molecular sieves were experimentally studied. Molecular sieves of 3 Å pore size own excellent hydrophilic characteristics and hardly absorb molecules other than water. Molecular sieves of 3 Å accompanied by two different vibrating types, rotary shaking and electromagnetic stirring, were used to remove initial water from the reactant mixture of feedstock oil in order to prevent excessive growth or breeding of microorganisms in the biofuel product. The physical structure of about 66% molecular sieves was significantly damaged due to shattered collision between the magnetic bar and molecular sieves during electromagnetic stirring for 1 h. The molecular sieves vibrated by the rotary shaker appeared to have relatively higher water-removal efficiency than those by the electromagnetic stirrer and by keeping the reactant mixture motionless by 6 and 5 wt.%, respectively. The structure of the molecular sieves vibrated by an electromagnetic stirrer and thereafter being dehydrated appeared much more irregular and damaged, and the weight loss accounted for as high as 19 wt.%. In contrast, the structure of the molecular sieves vibrated by a rotary shaker almost remained original ball-shaped, and the weight loss was much less after regenerative treatment for those molecular sieves. As a consequence, the water-removal process using molecular sieves vibrated by the rotary shaker is considered a competitive method during the biofuel production reaction to achieve a superior quality of biofuels.