The Effects of Nanoparticles- Zerovalent Iron on Sustainable Biomethane Production through Co-Digestion of Olive Mill Wastewater and Chicken Manure

Abstract

The impacts of nanoparticles-zerovalent iron (NP-ZVI) on anaerobic co-digestion (AcoD) were assessed. The production of biogas and methane (CH4), as well as the removal efficiency of volatile solids (VS) and contaminants were investigated in the AcoD of chicken manure (CM) and olive mill wastewater (OMWW) with the addition of NP-ZVI at different concentrations (10–50 mg/g VS) and different sizes resulting from various mixing volume ratios (MVR) of NaBH4:FeSO4.7H2O. The results show that NP-ZVI ≤ 30 mg/g VS at MVR-2:1, MVR-4:1, and MVR-6:1 improves the AcoD. In contrast to 40–50 mg/g VS of NP-ZVI, which caused an inhibitory impact in all of the AcoD stages, as well as a decrease in the contaminant’s removal efficiency, the concentration of 10–30 mg NP-ZVI/g VS at MVR-4:1 achieved a maximum improvement of CH4 by 21.09%, 20.32%, and 22.87%, respectively, and improved the biogas by 48.14%, 55.0%, and 80.09%, respectively, vs. the 0 additives. Supplementing AcoD with NP-ZVI at a concentration of 30 mg/g VS at MVR-4:1 resulted in maximum enhancement of the contaminant removal efficiency, with a total oxygen demand (TCOD) of up to 73.99%, turbidity up to 79.07%, color up to 53.41%, total solid (TS) up to 59.57%, and volatile solid (VS) up to 74.42%. It also improved the hydrolysis and acidification percentages by up to 86.67% and 51.3%, respectively.