Synthesis of Composites for the Removal of F- Anions

Author:

Saldaña-Robles Adriana1,Arcibar-Orozco Javier Antonio2ORCID,Guerrero-Mosqueda Luz Rocío1,Damián-Ascencio César Eduardo3,Marquez-Herrera Alfredo1ORCID,Corona Miguel4ORCID,Gallegos-Muñoz Armando3,Cano-Andrade Sergio3ORCID

Affiliation:

1. Department of Agricultural Engineering, University of Guanajuato, Ex Hacienda El Copal km 9, Irapuato 36500, Mexico

2. Centro de Innovación Aplicada en Tecnología Competitiva, CIATEC, Omega 201, Industrial Delta, Leon 37545, Mexico

3. Department of Mechanical Engineering, Universidad de Guanajuato, Salamanca 36885, Mexico

4. Mechanical Engineering and Management, Autonomous University of San Luis Potosi, COARA, San Luis Potosi 78000, Mexico

Abstract

This work presents the synthesis of amine and ferrihydrite functionalized graphene oxide for the removal of fluoride from water. The synthesis of the graphene oxide and the modified with amine groups is developed by following the modified Hummer’s method. Fourier transform infrared spectrometry, X-ray, Raman spectroscopy, thermogravimetric analysis, surface charge distribution, specific surface area and porosity, adsorption isotherms, and the van’t Hoff equation are used for the characterization of the synthesized materials. Results show that the addition of amines with ferrihydrite generates wrinkles on the surface layers, suggesting a successful incorporation of nitrogen onto the graphene oxide; and as a consequence, the adsorption capacity per unit area of the materials is increased.

Funder

University of Guanajuato

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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