High Sensitivity Electrochemical As (III) Sensor Based on Fe3O4/MoS2 Nanocomposites

Author:

Hu Haibing1ORCID,Hu Yunhu1,Xie Baozhu1,Zhu Jianxiong23

Affiliation:

1. Academy of Opto-Electric Technology, Special Display and Imaging Technology Innovation Center of Anhui Province, National Engineering Laboratory of Special Display Technology, State Key Laboratory of Advanced Display Technology, Collaborative Innovation Center of Advanced Display Technology, Anhui Key Laboratory of Advanced Imaging and Display Technology, Opto-Electric Display Industry Innovation Center, Anhui Province Key Laboratory of Measuring Theory and Precision Instrument, School of Instrument Science and Optoelectronics Engineering, Hefei University of Technology, Hefei 230009, China

2. School of Mechanical Engineering, Southeast University, Nanjing 211189, China

3. Engineering Research Center of New Light Sources Technology and Equipment, Ministry of Education, Nanjing 211189, China

Abstract

Currently, heavy metal ion pollution in water is becoming more and more common, especially As (III), which is a serious threat to human health. In this experiment, a glassy carbon electrode modified with Fe3O4/MoS2 nanocomposites was used to select the square wave voltammetry (SWV) electrochemical detection method for the detection of trace As (III) in water. Scanning electron microscopy (SEM) and X-ray diffraction (XRD) showed that Fe3O4 nanoparticles were uniformly attached to the surface of MoS2 and were not easily agglomerated. Cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) showed that Fe3O4/MoS2 has higher sensitivity and conductivity. After optimizing the experimental conditions, the Fe3O4/MoS2-modified glassy carbon electrode exhibited high sensitivity (3.67 μA/ppb) and a low detection limit (0.70 ppb), as well as excellent interference resistance and stability for As (III).

Funder

Fundamental Research Funds for the Central Universities

Ministry of Education

National Natural Science Foundation of Jiangsu Province

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

Reference42 articles.

1. Toxicological principles of metal carcinogenesis with special emphasis on cadmium;Waalkes;Crit. Rev. Toxicol.,1992

2. Arsenic round the world: A review;Mandal;Talanta,2002

3. Mercury, arsenic, lead, cadmium, and selenium residues in fish, 1971-73—National Pesticide Monitoring Program;Walsh;Pestic. Monit. J.,1977

4. Shimizu, F.M., Braunger, M.L., and Riul, A. (2019). Heavy Metal/Toxins Detection Using Electronic Tongues. Chemosensors, 7.

5. Voltammetric determination of inorganic arsenic;Liu;TrAC Trends Anal. Chem.,2014

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3