Volatile Organic Compounds on Rhodes Island, Greece: Implications for Outdoor and Indoor Human Exposure

Abstract

Volatile organic compounds (VOC) are considered a class of pollutants with a significant presence in indoor and outdoor air and serious health effects. The aim of this study was to measure and evaluate the levels of outdoor and indoor VOCs at selected sites on Rhodes Island, Greece, during the cold and warm periods of 2023. Spatial and seasonal variations were evaluated; moreover, cancer and non-cancer inhalation risks were assessed. For this purpose, simultaneous indoor-outdoor air sampling was carried out on the island of Rhodes. VOCs were determined by Thermal Desorption—Gas Chromatography/Mass Spectroscopy (TD-GC/MS). Fifty-six VOCs with frequencies ≥ 50% were further considered. VOC concentrations (∑56VOCs) at all sites were found to be higher in the warm period. In the warm and cold sampling periods, the highest concentrations were found at the port of Rhodes City, while total VOC concentrations were dominated by alkanes. The Positive Matrix Factorization (PMF) model was applied to identify the VOC emission sources. Non-cancer and cancer risks for adults were within the safe levels.