Pollution and Health Risk Assessment of Potentially Toxic Elements in Groundwater in the Kǒnqi River Basin (NW China)

Abstract

Potentially toxic elements (PTEs) pose a significant threat to the groundwater system and human health. Pollution and the potential risks of PTEs in groundwater in the Kǒnqi River Basin (KRB) of the northwest arid zones of China are still unknown. A total of 53 groundwater samples containing eight PTEs (Al, As, Cd, Cu, Mn, Pb, Se, and Zn) were collected from the KRB, and the pollution levels and probabilistic health risks caused by PTEs were assessed based on the Nemerow Index (NI) method and the health risk assessment model. The results revealed that the mean contents of Al, As, and Mn in the groundwater surpassed the Class III threshold of the Standard for Groundwater Quality of China. The overall pollution levels of the investigated PTEs in the groundwater fall into the moderate pollution level. The spatial distributions of contents and pollution levels of different PTEs in the groundwater were different. Health risk assessment indicated that all the investigated PTEs in groundwater in the KRB may pose a probabilistic non-carcinogenic health risk for both adults and children. Moreover, As may pose a non-carcinogenic health risk, whereas the non-carcinogenic health risk posed by the other seven PTEs in groundwater will not have the non-carcinogenic risks. Furthermore, As falls into the low carcinogenic risk level, whereas Cd falls into the very low carcinogenic risk level. Overall, As was confirmed as the dominant pollution factor and health risk factor of groundwater in the KRB. Results of this study provide the scientific basis needed for the prevention and control of PTE pollution in groundwater.