Effect of Catalyst Inlet Flow Field Distribution Characteristics on Outlet NO Concentration Distribution in SCR Denitration Reactor Based on Monte Carlo Method

Abstract

Selective catalytic reduction (SCR) technology plays a crucial role in flue gas denitration. The nonuniform distribution of catalyst inlet parameters causes the nonuniform distribution of NO concentration at the outlet, thus affecting accuracy of ammonia injection. Regarding this issue, this paper describes the impacts of nonuniform velocity and temperature on both the confidence of NO concentration measured at a single measuring point at the outlet and the denitration efficiency, which can provide a basis for structural optimization of SCR denitration reactor and decrease in ammonia slip. The random distribution form of velocity and temperature above the catalyst layer are derived from the actual gas volume and the actual SCR reactor model, and then the catalyst inlet boundary conditions were generated with different relative standard deviation of velocity and temperature accordingly. The confidence of outlet NO concentration measurement results can be counted by means of Monte Carlo simulation. Finally, the relation model can be obtained to calculate the confidence of outlet NO concentration measurement results at different working conditions. The results show that within the gas volume range of this work, in order to ensure the confidence of the NO concentration measurement results, the relative standard deviation of temperature before the catalyst inlet must be within 0.005 and the relative standard deviation of velocity before the catalyst inlet must be within 0.1. With the increase in relative standard difference in temperature, there is a slight decrease in the efficiency of denitration. With the different mean value of temperature, the variation range of denitration efficiency is similar to that of temperature-relative standard difference. With the different mean value of velocity, the deviation range of corresponding efficiency is similar to that of the temperature-relative standard difference. When the relative standard difference in velocity increases, the denitration efficiency decreases slightly. The greater velocity value, the decreasing range of denitration efficiency is larger than the variation range of relative standard difference in velocity.