Characteristics and Provenance Implications of Rare Earth Elements and Nd Isotope in PM2.5 in a Coastal City of Southeastern China

Abstract

The source apportionment of fine particulate matters, especially PM2.5, has drawn great attention worldwide. Since rare earth elements (REEs) and Nd isotopes can serve as source tracers, in this study, the characteristics and provenance implications of REEs and Nd isotopes in PM2.5 of four seasons in Xiamen city, China, were investigated. The range of the ratios of ΣREE to PM2.5 was 1.04 × 10−5 to 8.06 × 10−4, and the mean concentration of REEs in PM2.5 were in the order of spring > autumn > winter > summer. According to the geoaccumulation index (Igeo), spring was the season in which anthropogenic sources had the greatest impact on the REEs in PM2.5. The chondrite-normalized REE distribution patterns exhibited light rare earth elements (LREEs, including La, Ce, Pr, Nd, Pm, Sm and Eu) enrichment and a flat heavy rare earth elements (HREEs, including Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu) pattern. Significant negative Eu anomalies and no significant Ce anomalies were observed in the PM2.5. The results of La-Ce-Sm ternary plots indicated that the REEs in the PM2.5 might be related to both natural and anthropogenic sources. Combined with the Nd isotope, the 143Nd/144Nd versus Ce/Ce* plot further illustrated that the REEs in the PM2.5 seemed to mostly originate from multiple potential sources, in which vehicle exhaust emissions, coal burning and cement dust made a great contribution to REEs in PM2.5.