Compositions, Sources, and Aging Processes of Aerosol Particles during Winter Hazes in an Inland Megacity of NW China

Abstract

As one of the largest inland megacities in Northwest (NW) China, Xi’an has been facing serious regional haze frequently, especially during winter. The composition of aerosols in Xi’an is highly complex due to its unique basinal topography and unique meteorological conditions. In this study, we characterized the morphology, size, and composition of individual aerosol particles collected during regional haze events at an urban site in Xi’an using Transmission Electron Microscopy (TEM) coupled with Energy-Dispersive X-ray Spectrometry (EDX). Six types of particles were identified based on their morphology and chemical composition, including organic (41.88%), sulfate (32.36%), soot (8.33%), mineral (7.91%), K-rich (5.13%), and fly ash particles (4.49%). These results demonstrate that the organic particles made a larger contribution to haze formation than the secondary inorganic particles during the sampling period. Size distribution and dominance suggest that organic and sulfate particles exert major control on the variation trends of particle size in haze. The coating thickness of organic-cored particles was about 369 nm and that of sulfate-cored particles was about 322 nm, implying that the organic particles were more aged than the sulfate particles. The results presented in this study provide further insights into understanding haze particle formation.