Pseudo-Desublimation of AdBlue Microdroplets through Selective Catalytic Reduction System Microchannels and Surfaces

Abstract

In the present paper, the occurrence and development of the pseudo-desublimation process of AdBlue microdroplets in the microchannels and surfaces of catalytic reduction systems (SCR) are reported. In order to understand how the pseudo-desublimation process develops, the influence of heat flux values on the heat transfer of AdBlue injection was analysed, taking into account the structure of the microchannels inside the SCR and the overall configuration of the installation. The evolution of the AdBlue vapour flow in the SCR system was simulated, as well as the temperature variation along an SCR microchannel through which the mixture flows. An experimental set-up was designed in order to visualise and interpret the processes at the onset of pseudo-desublimation. The results described in this paper confirm the existence of a pseudo-desublimation process that occurs only under certain temperature conditions when AdBlue is injected into SCR systems. The characteristics of the crystals formed and their growth rate depend on the working temperature, which could be controlled by efficient preheating methods immediately after engine start. A better understanding of the process will allow the development of methods of avoiding solid depositions on SCR system components, which has a direct impact on SCR catalyst performance and durability.