Relaxation Functions Interpolating the Cole–Cole and Kohlrausch–Williams–Watts Dielectric Relaxation Models

Author:

Duan Lingjie1,Duan Junsheng2ORCID,Li Ming34ORCID

Affiliation:

1. School of Materials Science and Engineering, Shanghai Institute of Technology, Shanghai 201418, China

2. School of Sciences, Shanghai Institute of Technology, Shanghai 201418, China

3. Ocean College, Zhejiang University, Hangzhou 310012, China

4. Village 1, East China Normal University, Shanghai 200062, China

Abstract

To describe non-Debye relaxation phenomena observed in dielectric materials, the Cole–Cole (CC) relaxation model in the frequency domain and the Kohlrausch–Williams–Watts (KWW) relaxation model in the time domain were introduced in the physics of dielectrics. In this paper, we propose a new relaxation model with two parameters besides a relaxation time by expressing the relaxation function in the time domain in terms of the Mittag–Leffler functions. The proposed model represents a group of non-Debye relaxation phenomena and shows a transition between the CC and the KWW models. The relaxation properties described by the new model are analyzed, including the response function, the normalized complex dielectric permittivity, dielectric storage and loss factors as well as the relaxation frequency and time spectral functions. The presented relaxation function has a concise form and is expected to be applied to more complex relaxation phenomena.

Publisher

MDPI AG

Subject

Physics and Astronomy (miscellaneous),General Mathematics,Chemistry (miscellaneous),Computer Science (miscellaneous)

Reference41 articles.

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5. A complex plane analysis of α-dispersions in some polymer systems;Havriliak;J. Polym. Sci. C Polym. Symp.,1966

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