Corrosion Resistance of Coatings Based on Chromium and Aluminum of Titanium Alloy Ti-6Al-4V

Author:

Loskutova Tetiana12ORCID,Scheffler Michael2ORCID,Pavlenko Ivan34ORCID,Zidek Kamil4ORCID,Pohrebova Inna5,Kharchenko Nadiia6ORCID,Smokovych Iryna7,Dudka Oleksandr1,Palyukh Volodymyr8,Ivanov Vitalii910ORCID,Kononenko Yaroslav1

Affiliation:

1. Department of Physical Materials Science and Heat Treatment, Y.O. Paton Institute of Materials Science and Welding, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37 Beresteiskyi Ave., 03056 Kyiv, Ukraine

2. Faculty of Mechanical Engineering, Institute for Materials and Joining Technology, Otto-von-Guericke University Magdeburg, 2 Universitätsplatz, 39106 Magdeburg, Germany

3. Department of Computational Mechanics Named after Volodymyr Martsynkovskyy, Faculty of Technical Systems and Energy Efficient Technologies, Sumy State University, 116 Kharkivska St., 40007 Sumy, Ukraine

4. Department of Industrial Engineering and Informatics, Faculty of Manufacturing Technologies with a Seat in Presov, Technical University of Kosice, 1 Bayerova St., 08001 Presov, Slovakia

5. Department of Electrochemical Production Technology, Faculty of Chemical Technology, National Technical University of Ukraine “Igor Sikorsky Kyiv Polytechnic Institute”, 37 Beresteiskyi Ave., 03056 Kyiv, Ukraine

6. Department of Applied Materials Science and Technology of Constructional Materials, Faculty of Technical Systems and Energy Efficient Technologies, Sumy State University, 116 Kharkivska St., 40007 Sumy, Ukraine

7. thyssenkrupp Materials Trading GmbH, 1 Thyssenkrupp Allee, 46143 Essen, Germany

8. Department of Strength of Materials and Structural Mechanics, Institute of Civil Engineering and Building Systems, Lviv Polytechnic National University, 2 Karpinskoho St., 79013 Lviv, Ukraine

9. Department of Manufacturing Engineering, Machines and Tools, Faculty of Technical Systems and Energy Efficient Technologies, Sumy State University, 116 Kharkivska St., 40007 Sumy, Ukraine

10. Department of Automobile and Manufacturing Technologies, Faculty of Manufacturing Technologies with a Seat in Presov, Technical University of Kosice, 1 Bayerova St., 08001 Presov, Slovakia

Abstract

Improvement of wear, corrosion, and heat-resistant properties of coatings to expand the operational capabilities of metals and alloys is an urgent problem for modern enterprises. Diffusion titanium, chromium, and aluminum-based coatings are widely used to solve this challenge. The article aims to obtain the corrosion-electrochemical properties and increase the microhardness of the obtained coatings compared with the initial Ti-6Al-4V alloy. For this purpose, corrosion resistance, massometric tests, and microstructural analysis were applied, considering various aggressive environments (acids, sodium carbonate, and hydrogen peroxide) at different concentrations, treatment temperatures, and saturation times. As a result, corrosion rates, polarization curves, and X-ray microstructures of the uncoated and coated Ti-6Al-4V titanium alloy samples were obtained. Histograms of corrosion inhibition ratio for the chromium–aluminum coatings in various environments were discussed. Overall, the microhardness of the obtained coatings was increased 2.3 times compared with the initial Ti-6Al-4V alloy. The corrosion-resistant chromaluminizing alloy in aqueous solutions of organic acids and hydrogen peroxide was recommended for practical application in conditions of exposure to titanium products.

Funder

Slovak Research and Development Agency

Ministry of Education, Science, Research and Sport of the Slovak Republic

EU NextGenerationEU through the Recovery and Resilience Plan for Slovakia

Publisher

MDPI AG

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