Promoting Effect of H+ and Other Factors on NO Removal by Using Acidic NaClO2 Solution

Author:

Gong Pijian,Li Xinxue

Abstract

In this study, NaClO2 was selected as a denitration oxidant. In order to clarify the mechanism of NaClO2 as an oxidation agent for NO removal efficiency, the effects of H+ and other factors (NaClO2 concentration, temperature, and the other gas) on the NO removal efficiency were investigated. NaClO2 showed a promotional ability on NO removal, whose efficiency increased with the increase of NaClO2 concentration. One hundred percent removal efficiency of NO could be achieved when the NaClO2 concentration was 0.014 mol/L. Furthermore, raising the reaction temperature benefited the removal of NO. The lower the pH, the better the NO removal efficiency. The promoting effect of H+ on the NO removal was studied by the Nernst equation, ionic polarization, and the generation of ClO2. Under the optimal conditions, the best removal efficiency of NO was 100%. Based on the experimental results, the reaction mechanism was finally speculated.

Funder

National Natural Science Foundation of China

Publisher

MDPI AG

Subject

Energy (miscellaneous),Energy Engineering and Power Technology,Renewable Energy, Sustainability and the Environment,Electrical and Electronic Engineering,Control and Optimization,Engineering (miscellaneous)

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