Comparison of Fenton and Ozone Oxidation for Pretreatment of Petrochemical Wastewater: COD Removal and Biodegradability Improvement Mechanism

Abstract

Cost-effective pretreatment of highly concentrated and bio-refractory petrochemical wastewater to improve biodegradability is of significant importance, but remains challenging. This study compared the pretreatment of petrochemical wastewater by two commonly used chemical advanced oxidation technologies (Fenton and ozone oxidation), and the mechanisms of biodegradability improvement of pretreated wastewater were explored. The obtained results showed that in the Fenton oxidation system, the COD removal of petrochemical wastewater was 89.8%, BOD5 decreased from 303.66 mg/L to 155.49 mg/L, and BOD5/COD (B/C) increased from 0.052 to 0.62 after 60 min under the condition of 120 mg/L Fe2+ and 500 mg/L H2O2, with a treatment cost of about 1.78 $/kgCOD. In the ozone oxidation system, the COD removal of petrochemical wastewater was 59.4%, BOD5 increased from 127.86 mg/L to 409.28 mg/L, and B/C increased from 0.052 to 0.41 after 60 min at an ozone flow rate of 80 mL/min with a treatment cost of approximately 1.96 $/kgCOD. The petrochemical wastewater treated by both processes meets biodegradable standards. The GC–MS analysis suggested that some refractory pollutants could be effectively removed by ozone oxidation, but these pollutants could be effectively degraded by hydroxyl radicals (•OH) produced by the Fenton reaction. In summary, compared with ozone oxidation, petrochemical wastewater pretreated with Fenton oxidation had high COD removal efficiency and biodegradability, and the treatment cost of Fenton oxidation was also lower than that of ozone oxidation.