Investigation of Molecular Mean Free Path, Molecular Kinetic Energy, and Molecular Polarity Affecting Knudsen Diffusivity along Pore Channels

Abstract

The effective purification of corrosive gases at the cathode air stream side is essential for proton exchange membrane fuel cells’ performance in real-world applications. Gas molecular diffusion depth along the pore channel is a sufficient parameter that determines the effectiveness of the porous purification media. The collision between gas molecules and pore surfaces is the crucial determinant of the diffusion depth. An analytical model was developed to predict the gas molecular diffusion depth in the pore channels. Two different crystal sizes of UiO-66 were synthesized to validate against the model result and empirically determine the diffusion depths. The parametric effects of the mean free path, molecular kinetic energy, and molecular polarity on molecular diffusivity were assessed. A smaller molecular mean free path and greater molecular kinetic energy were favorable for larger diffusion depth, owing to the fewer collisions and enhanced bounces after collisions. Greater molecular polarity led to shorter diffusion depth due to the enhanced van der Waals force between molecules and pore surfaces.