Dried Leaves Powder of Adiantum capillus-veneris as an Efficient Biosorbent for Hazardous Crystal Violet Dye from Water Resources

Author:

Gul Salma1,Gul Shehla1,Gul Hajera2ORCID,Khitab Fatima2,Khattak Rozina2ORCID,Khan Muhammad3,Ullah Rizwan4,Ullah Rooh5,Wasil Zahida2,Krauklis Andrey6ORCID,Zekker Ivar7

Affiliation:

1. Department of Chemistry, Women University Swabi, Swabi 22101, Pakistan

2. Department of Chemistry, Shaheed Benazir Bhutto Women University, Peshawar 25000, Pakistan

3. Department of Chemistry, University of Malakand, Chakdara 18800, Pakistan

4. National Center of Excellence in Physical Chemistry, University of Peshawar, Peshawar 25120, Pakistan

5. Department of Chemistry, University of Turbat, Balochistan 12120, Pakistan

6. Institute for Mechanics of Materials, University of Latvia, Jelgavas Street 3, LV-1004 Riga, Latvia

7. Institute of Chemistry, University of Tartu, 14a Ravila St., 50411 Tartu, Estonia

Abstract

The dyeing industry uses many chemicals and dyes. After the dying process is completed, they release a significant amount of dyes in wastewater. The dyes’ color emissions are extremely poisonous and dangerous for aquatic and terrestrial life. Due to the toxic nature of dyes, the current study was carried out to evaluate whether it would be effective to employ an adsorption procedure with leaves from the Adiantum capillus-veneris plant as an adsorbent to remove commonly used textile dyes from an aqueous dye solution and wastewater. The effect of pH, concentration, time and the adsorbent dose on the adsorption process was studied in order to determine the maximum adsorption under ideal conditions. The selected pH was 3; the optimum concentration was 30 ppm with a contact time of 90 min and the optimized adsorbent dose was 60 mg. The absorbent under study showed excellent results when compared with commercial adsorbents i.e., animal charcoal and silica gel. The leaves of the Adiantum capillus-veneris plant revealed a maximum removal of 90.36 percent crystal violet dye (adsorption capacity (Qe) 9.05 mg/g) without any treatment to activate or alter the surface chemistry of the biosorbent. Its effectiveness was also tested with water gathered from several sources, including canal water, tap water, distilled water, and saline water, to determine whether it was practical. In both the canal and the tap water, the adsorbent displayed good removal efficiency. From the results of the current study, it can be inferred that the leaves of the Adiantum capillus-veneris plant are a reasonably priced biosorbent that can be used to remove toxic dyes from wastewater to protect water bodies from toxic pollution and can be used to treat industrial wastewater directly.

Publisher

MDPI AG

Subject

Filtration and Separation,Analytical Chemistry

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