Effect of the Zn/Mg Ratio on Microstructures, Mechanical Properties and Corrosion Performances of Al-Zn-Mg Alloys

Abstract

The effect of the Zn/Mg ratio on microstructures, mechanical properties and corrosion performances of Al-Zn-Mg alloys was studied. Microstructures were characterized using the optical microscope (OM), scanning electron microscope (SEM) and transmission electron microscope (TEM). Tensile tests, intergranular corrosion (IGC) and stress corrosion cracking (SCC) tests were conducted to study the properties. Microstructures results indicated that with the decrease of the Zn/Mg ratio, the recrystallization proportion and the fraction of second phase decreased, while the size of η’ (MgZn2) phases in grain interior also significantly decreased. The number density of η’ phases in grain interior increased and grain boundary precipitates developed discontinuous distribution with the decrease of the Zn/Mg ratio. These microstructures contributed to the significant improvement of the strength and corrosion resistance. The tensile strength and yield strength increased by 34.1% and 47.4%, respectively, with the Zn/Mg ratio decreased from 11.4 to 6.1. Calculating results indicated that the enhancement of strength mainly contributed from the solid-solution strengthening, grain-boundary strengthening and precipitation strengthening. The intergranular corrosion degree was greatly relieved and the stress corrosion sensitivity index decreased from 0.031 to 0.007 with the Zn/Mg ratio decreased from 11.4 to 6.1.