Effect of Stearyl Methacrylate Comonomer on the Mechanical and Physical Properties of Dimethacrylate-Based Dental Resins

Abstract

This study evaluated the effect of stearyl methacrylate addition on the physical and mechanical properties of bisphenol A glycidyl methacrylate- and triethylene glycol dimethacrylate-based polymers, which are traditionally used in dental applications. Methacrylate-based monomer compositions are polymerized under the visible blue light spectrum. An analysis of double bond conversion, surface microhardness test, three-point bending test and water sorption and water solubility were tested to determine the physical and mechanical properties of the dental polymers. The results indicated that stearyl methacrylate addition up to 25 wt% reduced the water sorption of the polymers. At amounts of stearyl methacrylate higher than 25 wt%, the solubility of the polymer in water increases due to the monofunctional structure. Mechanical properties are negatively affected by the increasing stearyl methacrylate ratio. Further, the addition of stearyl methacrylate slightly increased thermal stability. As such, the amount of stearyl methacrylate in a polymer composition is critical for the optimization of its mechanical and physical properties. According to the results, the amount of stearyl methacrylate has to be between 12.5–25 wt%.