Fe-Bound Organic Carbon and Sorption of Aromatic Dissolved Organic Carbon in Surface Soil: Comparing a Forest, a Cropland, and a Pasture Soil in the Central Appalachian Region, West Virginia, U.S.A

Abstract

The essential roles of Fe oxides in stabilizing long-term soil organic carbon (SOC), especially aromatic dissolved organic carbon (DOCaro), are well-established in forest soils and sediments. We chose to focus on these processes in agricultural soils in which the input and translocation of native DOC to deeper soils are impacted by management practices. We quantified SOC, Fe oxide bound SOC (Fe-bound OC), and the DOCaro sorption in a forest, a cropland, and a pasture soil at 0–10 and 10–25 cm. Significantly larger amounts of Fe oxides in the cropland soil were observed compared to the forest and pasture soils at both depths (p < 0.05). Land management practices and depth both significantly influenced the Fe-bound OC percentage (p < 0.05). Larger maximum sorptions of DOC in the cropland (315.0 mg kg−1) and pasture (395.0 mg kg−1) soils than the forest soil (96.6 mg kg−1) at 10–25 cm weres found. DOCaro sorption decreased in the three soils at 0–10 cm (slope of −0.002 to −0.014 L2 mg−2 m−1) as well as the forest soil at 10–25 cm (−0.016 L2 mg−2 m−1) with increasing equilibrium DOC concentration. Conversely, the cropland and pasture soils at 10–25 cm increased (0.012 to 0.014 L2 mg−2 m−1). The different sorption behaviors of DOCaro in these surface soils indicate that the forest, cropland, and pasture-managed soils may have more complex and various sorption behaviors in stabilizing DOCaro and non-DOCaro.