Pyraclostrobin Removal in Pilot-Scale Horizontal Subsurface Flow Constructed Wetlands and in Porous Media Filters

Abstract

Pyraclostrobin is a fungicide extensively used for the control of various fungal diseases and is frequently detected in environmental samples. Natural systems, such as constructed wetlands (CWs) and gravity filters, are effective and environmentally friendly treatment systems, which can reduce or eliminate pesticides from the environment. The aim of this study was to investigate the capacity of two pilot-scale CWs (porous media: cobbles and fine gravel, planted with Phragmites australis) and six gravity filters (filling material: bauxite, carbonate gravel and zeolite) to remove pyraclostrobin from polluted water originating from spraying equipment rinsing sites. For this, experiments were conducted to test the performance of the above natural systems in removing this fungicide. The results showed that the mean percent pyraclostrobin removal efficiencies for cobbles and fine gravel CW units were 56.7% and 75.2%, respectively, and the mean percent removals for HRTs of 6 and 8 days were 68.7% and 62.8%, respectively. The mean removal efficiencies for the bauxite, carbonate gravel and zeolite filter units were 32.5%, 36.7% and 61.2%, respectively, and the mean percent removals for HRTs 2, 4 and 8 days were 39.9%, 43.4% and 44.1%, respectively. Regarding the feeding strategy, the mean removal values of pyraclostrobin in gravity filter units were 43.44% and 40.80% for continuous and batch feeding, respectively. Thus, these systems can be used in rural areas for the treatment of spraying equipment rinsing water.