Affiliation:
1. College of Pharmacy, Jiamusi University, Jiamusi 154007, China
2. School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China
Abstract
By using melamine as a precursor for the copolymerization process, g-C3N4 and g-C3N4/TCNQ/Eu complexes with various amounts of doping were created. These complexes were then examined using XRD, FT-IR, SEM, TEM, XPS, PL, UV-vis, and I-T. The degradation rates of pefloxacin (PEF), enrofloxacin (ENR), and ciprofloxacin (CIP) were 91.1%, 90.8%, and 93.2% under visible light (λ > 550 nm). The photocatalytic performance of the composite was analyzed, and the best effect was obtained for CIP photocatalysis when Eu doping was 3 mg at 20 °C and pH 7. Kinetic analysis showed that there was a linear relationship between the sample and the photocatalytic time, and the degradation rate was about 5 times that of g-C3N4. The cyclic stability of the g-C3N4/TCNQ/Eu composite sample was found to be good through repeated experiments. UPLC-MS visualizes the degradation process of CIP. The extremely low stability of piperazine ring induced subsequent degradation, followed by the fracture of quinolone ring promoting the complete decomposition of CIP.
Funder
Department of Scientific Research Project in Heilongjiang Province
Basic Scientific Research Project of Heilongjiang Province
Jiamusi University Doctoral Special Scientific Research Foundation
Jiamusi University Horizontal Research Project
Innovation and Entrepreneurship Project for College Students in Heilongjiang Province
Subject
Electrical and Electronic Engineering,Mechanical Engineering,Control and Systems Engineering