Microwave Synthesis of Au Nanoparticles in the Presence of Tetrahydrothiophenocucurbituril

Author:

Atthar Asma S.1,Saha Shreya1,Abdulrahman Ahmed1,Day Anthony I.1ORCID

Affiliation:

1. Chemistry, School of Science, University of New South Wales Canberra, Australian Defence Force Academy, Canberra, ACT 2600, Australia

Abstract

The preparation of gold nanoparticles (AuNPs) from tetrachloroauric acid in the presence of tetrahydrothiophenocucurbit[n]uril (THTmQ[n]) has been effectively achieved in a microwave reactor. The reaction was performed in the presence of an excess of the tetrahydrothiopheno function in a partial reductant role, while the remainder formed AuNP-THTmQ[n] conjugates after the reduction was completed with formic acid. An affinity for the AuNPs by the THTmQ[n] was observed in the purification of the NPs via centrifugation, removal of the supernatant and resuspension of the conjugate.

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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