Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors-Reference-Cited by-同舟云学术

Supramolecular Diiodine-Bromostannate(IV) Complexes: Narrow Bandgap Semiconductors

Published:2022-06-16 Issue:12 Volume:27 Page:3859
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Korobeynikov Nikita A.^ORCID,Usoltsev Andrey N.,Abramov Pavel A.^ORCID,Sokolov Maxim N.^ORCID,Adonin Sergey A.

Abstract

Three supramolecular bromostannates(IV) with “trapped” diiodine molecules, Cat2{[SnBr6](I2)} (Cat = Me4N+ (1), 1-MePy+ (2) and 4-MePyH (3)), were synthesized. In all cases, I2 linkers are connected with bromide ligands via halogen···halogen non-covalent interactions. Articles 1–3 were studied using Raman spectroscopy, thermogravimetric analysis, and diffuse reflectance spectroscopy. The latter indicates that 1–3 are narrow band gap semiconductors.

Funder

Russian Science Foundation

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/27/12/3859/pdf

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5. (C3N2H5)3Sb2I9 and (C3N2H5)3Bi2I9: ferroelastic lead-free hybrid perovskite-like materials as potential semiconducting absorbers

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