W-SBA-15 as an Effective Catalyst for the Epoxidation of 1,5,9-Cyclododecatriene-Reference-Cited by-同舟云学术

W-SBA-15 as an Effective Catalyst for the Epoxidation of 1,5,9-Cyclododecatriene

Published:2022-12-10 Issue:24 Volume:27 Page:8769
ISSN:1420-3049
Container-title:Molecules
language:en
Short-container-title:Molecules

Author:

Kujbida Marcin^ORCID,Wróblewska Agnieszka^ORCID,Lewandowski Grzegorz,Miądlicki Piotr^ORCID,Michalkiewicz Beata^ORCID

Abstract

The results of a study on the epoxidation of 1,5,9-cyclododecatriene (CDT) on a W-SBA-15 catalyst using the batch and half-periodic methods are presented. During this study, the activity of the W-SBA-15 catalyst was compared to that of the Ti-SBA-15 catalyst, and the W-SBA-15 catalyst was found to be about 20 times more active than the Ti-SBA-15 catalyst. The highest CDT conversion so far, amounting to 86 mol%, was obtained after carrying out the 4 h epoxidation process. Conducting the studied process using the semi-batch method did not result in the significant improvement in value functions describing this process (CDT conversion and selectivity of CDT transformation to ECDD), but the fastest H2O2 dosing rate (246 µL/h) allowed us to obtain 9 mol% higher CDT conversion in comparison to the batch method.

Funder

Rector of the West Pomeranian University of Technology in Szczecin for PhD students of the Doctoral School

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

Link

https://www.mdpi.com/1420-3049/27/24/8769/pdf

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