Novel Synthesis of Dihydroisoxazoles by p-TsOH-Participated 1,3-Dipolar Cycloaddition of Dipolarophiles withα-Nitroketones

Author:

Yang Caiyun1,Hu Sirou1,Pan Xinhui12,Yang Ke1,Zhang Ke1,Liu Qingguang1,Xin Xiaobing1,Li Jie1,Wang Jinhui1,Yang Xiaoda12

Affiliation:

1. Key Laboratory of Xinjiang Phytomedicine Resource and Utilisation, Ministry of Education, School of Pharmaceutical Sciences, Shihezi University, Shihezi 832002, China

2. Stake Key Laboratory of Natural and Biomimetic Drugs, Department of Chemical Biology, School of Pharmaceutical Sciences, Peking University, Beijing 100191, China

Abstract

This article reports in detail a method for the synthesis of 3-benzoxoxazoline by the reaction of alkenes (alkynes) and a variety of α-nitroketones in the presence of p-TsOH. The scope of alkenes is broad, including different alkenes and the alkyne. This reaction provides a convenient and efficient synthetic method of 3-benzoylisoxazolines.

Funder

National Natural Science Foundation of China

The Open Project of Stake Key Laboratory of Natural and Biomimetic Drugs, Peking University

The Open Project of Key Laboratory of Xinjiang Phytomedicine Resource and Utilization, Ministry of Education

Youth Innovative Talent Cultivation Projects of Shihezi University

The National Innovation and Entrepreneurship Training Program for Undergraduate

The Open Sharing Fund for the Large-scale Instruments and Equipments of Shihezi University

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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