Affiliation:
1. Centre Interdisciplinaire de Nanoscience de Marseille (CINaM), UMR 7325 CNRS Aix-Marseille Université, Campus de Luminy, Case 913, F-13288 Marseille, France
Abstract
Tetraamino-tetranitro-azacalixarene 5 is at the crossroad of two different families of compounds depending on the conditions and the agent used to reduce the NO2 groups: (1) azacalixphyrin 7 in neutral medium, or (2) phenazinium of type 8 in acidic medium. The key role of the N-substituted amino functions at the periphery is highlighted by investigating octaaminoazacalixarene as a model compound, and by using the corresponding tetrahydroxy-tetranitro-azacalixarene 15 as a precursor, which behaves differently.
Funder
Centre National de la Recherche Scientifique
Ministère de l’Enseignement supérieur et la Recherche
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
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1 articles.
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