The Development and Synthesis of a CdZnS @Metal–Organic Framework ZIF-8 for the Highly Efficient Photocatalytic Degradation of Organic Dyes

Author:

Hong Liu1,Cao Jiaming1,Zhang Wenlong1,Jiang Tao1,Pan Guohao1,Wu Yun1

Affiliation:

1. School of Energy Materials and Chemical Engineering, Hefei University, Hefei 230601, China

Abstract

The development of photocatalysts for organic degradation is a hot research topic. In this study, CdZnS was selected as the carrier, and ZIF-8 was combined with it to explore the photocatalytic performance of the composite. In addition, the compound material, CdZnS@ZIF-8, was used as a photocatalyst for the decomposition of methylene blue dye, and the performance of pure CdZnS and pure ZIF-8 was compared. The photocatalytic efficiency of CdZnS@ZIF-8 was significantly higher than that of the other two. In the experimental reaction, the amount of catalyst was 0.04 g, the pH value was 7, the initial concentration of methylene blue aqueous solution was 20 mg/L, and the degradation of methylene blue in 50 mL aqueous solution could reach 99.5% under visible light irradiation for 90 min, showing excellent photocatalytic efficiency in the visible light range. It demonstrated excellent photocatalytic function in the visible light region, and the electron transfer phenomenon at the interface occurred in the het-junction and the separation of the photo-generating electron–hole as an electron acceptor of ZIF-8 further promoted the photocatalytic effect.

Funder

Nature Science Foundation

Excellent Young Talents Fund Program of Higher Education Institutions of Anhui Province

National Natural Science Foundation of China

Natural Science Foundation of Hefei university

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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