Graphene Aerogel Growth on Functionalized Carbon Fibers

Abstract

Graphene aerogel (GA) is a lightweight, porous, environmentally friendly, 3D structured material with interesting properties, such as electrical conductivity, a high surface area, and chemical stability, which make it a powerful tool in energy storage, sensing, catalyst support, or environmental applications. However, the poor mechanical stability that often characterizes graphene aerogels is a serious obstacle for their use in such applications. Therefore, we report here the successful mechanical reinforcement of GA with carbon fibers (CFs) by combining reduced graphene oxide (rGO) and CFs in a composite material. The surfaces of the CFs were first successfully desized and enriched with epoxy groups using epichloridrine. Epoxy-functionalized CFs (epoxy-CFs) were further covered by reduced graphene oxide (rGO) nanosheets, using triethylene tetramine (TETA) as a linker. The rGO-covered CFs were finally incorporated into the GA, affording a stiff monolithic aerogel composite. The as-prepared epoxy-CF-reinforced GA was characterized by spectroscopic and microscopic techniques and showed enhanced electrical conductivity and compressive strength. The improved electrical and mechanical properties of the GA-CFs composite could be used, among other things, as electrode material or strain sensor applications.