Author:
Gan Zubao,Cui Deyun,Zhang Hongyun,Feng Ying,Huang Liying,Gui Yingying,Gao Lu,Song Zhenlei
Abstract
(Ph3C)[BPh(F)4]-catalyzed Hosomi-Sakurai allylation of allylsilanes with β,γ-unsaturated α-ketoesters has been developed to give γ,γ-disubstituted α-ketoesters in high yields with excellent chemoselectivity. Preliminary mechanistic studies suggest that trityl cation dominates the catalysis, while the silyl cation plays a minor role.
Funder
the National Natural Science Foundation of China
the Science and Technology Department of Sichuan Province
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Cited by
2 articles.
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