Facile Synthesis of PdO.TiO2 Nanocomposite for Photoelectrochemical Oxygen Evolution Reaction

Author:

Altaf Amna,Sohail ManzarORCID,Nafady AymanORCID,Siddique Rashid G.,Shah Syed Shoaib Ahmad,Najam Tayyaba

Abstract

The rapid depletion of fossil fuels and environmental pollution has motivated scientists to cultivate renewable and green energy sources. The hydrogen economy is an emerging replacement for fossil fuels, and photocatalytic water splitting is a suitable strategy to produce clean hydrogen fuel. Herein, the photocatalyst (PdO.TiO2) is introduced as an accelerated photoelectrochemical oxygen evolution reaction (OER). The catalyst showed significant improvement in the current density magnitude from 0.89 (dark) to 4.27 mA/cm2 (light) during OER at 0.5 V applied potential. The as-synthesized material exhibits a Tafel slope of 170 mVdec−1 and efficiency of 0.25% at 0.93 V. The overall outcomes associated with the photocatalytic activity of PdO.TiO2 demonstrated that the catalyst is highly efficient, thereby encouraging researchers to explore more related catalysts for promoting facile OER.

Funder

Higher Education Commission (HEC), Pakistan

Publisher

MDPI AG

Subject

Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science

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