Cucumber (Cucumis sativus L.) Leaf Extract as a Green Corrosion Inhibitor for Carbon Steel in Acidic Solution: Electrochemical, Functional and Molecular Analysis

Abstract

An extract of cucumber leaves (ECSL) was prepared as a green corrosion inhibitor for carbon steel. Its carbon steel corrosion inhibition performance against 0.5 mol L−1 H2SO4 was investigated using electrochemical methods and scanning electron microscopy (SEM). Its composition was analyzed by gas chromatography and mass spectroscopy (GC−MS). Quantum chemical calculations and molecular dynamics simulations (MDS) were conducted to elucidate the adsorption mechanism of the inhibitor molecules on the carbon steel surface. The results indicated that the inhibition efficiency increases with its increasing concentration. The extract acted as a mixed type corrosion inhibitor, and its inhibition properties were ascribed to the geometric coverage effect induced by its adsorption on the metal surface in accordance with Langmuir’s law. The active components in the extract were identified as mainly organic compounds with functional groups such as aromatic moieties and heteroatoms. The inhibition activities of ECSL are delivered through the ability of the active components to adsorb on the metal surface through their functional groups to form a protective layer which hinders the contact of aggressive substances with carbon steel and thus suppresses its corrosion. This research provides an important reference for the design of green corrosion inhibitors based on plant waste materials.