Affiliation:
1. Departamento de Química, Facultad de Ciencias, Universidad de Burgos, 09001 Burgos, Spain
Abstract
In this work, we have prepared and characterized some gold compounds wearing a N-heterocyclic carbene (NHC) ligand as well as alkynyl derivatives with different substituents. The study of their electrochemical behavior reveals that these complexes show an irreversible wave at potentials ranging between −2.79 and −2.91 V, referenced to the ferrocenium/ferrocene pair. DFT calculations indicate that the reduction occurs mainly on the aryl−C≡C fragment. The cyclic voltammetry experiments under CO2 atmosphere show an increase in the faradaic current of the reduction wave compared to the experiments under argon atmosphere, indicating a possible catalytic activity towards the carbon dioxide reduction reaction (CO2RR).
Funder
Ministerio de Ciencia, Innovación y Universidades of Spain
Junta de Castilla y León, the Spanish Ministerio de Ciencia e Innovación MICIN
European Union Next Generation EU/PRTR