Abstract
Finite or periodic structures containing the cube motif can be synthesized and transformed into a variety of structures both at the theoretical and real, experimental level. The rhombellation topo-geometric operation may be used to transform the cube-shape into larger units and then build light (spongy) structures with larger voids. Hyper-clusters are polyhedral structures which nodes are polyhedral structures (the same or different ones). The paper presents some hypothetical spongy structures related to the cubic primitive pcu-net, with defects induced by cutting-off some atoms and/or bonds so that only corners are shared between two cubes. A diamondoid hyper-structure containing cube-coalesced corners was proposed for an eventual synthesis. The discussed structures are described in topological terms, particularly by sequential vertex connectivity and ring environment.
Subject
Chemistry (miscellaneous),Analytical Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Molecular Medicine,Drug Discovery,Pharmaceutical Science
Cited by
2 articles.
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1. Nano-structures as materials in biosciences;Journal of Molecular Structure;2021-01
2. Symmetry of hyper-adamantanes;Fullerenes, Nanotubes and Carbon Nanostructures;2020-03-28