A Self-Cleaning TiO2 Bacterial Cellulose Super-Hydrophilic Underwater Super-Oleophobic Composite Membrane for Efficient Oil–Water Separation

Abstract

Due to the increasingly serious problem of offshore oil spills, research related to oil–water separation has attracted more and more attention. Here, we prepared a super-hydrophilic/underwater super-oleophobic membrane (hereinafter referred to as BTA) using poly-dopamine (PDA) to adhesive TiO2 nanoparticles on the surface of bacterial cellulose, coated with sodium alienate by vacuum-assisted filtration technique. This demonstrates its excellent underwater super-oleophobic property. Its contact angle is about 153°. Remarkably, BTA has 99% separation efficiency. More importantly, BTA still showed excellent anti-pollution property under ultraviolet light after 20 cycles. BTA has the advantages of low cost, environmentally friendliness and good anti-fouling performance. We believe it can play an important role in dealing with problems related to oily wastewater.